Electrochemistry · Lecture · Intermediate

PEM Electrolyzer Model: Fundamentals and Theoretical Concepts

Chemical Engineering Guy24 minEnglish

Why watch it?

Before building a PEM electrolyzer unit operation in a process simulator, it helps to know what the model rests on. This third video in the Chemical Engineering Guy series made with Aspen Tech covers the cell model, mass-transfer models, thermodynamics, electrochemistry and overpotentials. Suited to students and process engineers preparing for simulation work. The presenter is not named in the description, and the channel links to paid training material.

This introduction is based on the video’s YouTube description and catalogue details.

What you will learn

The viewer can relate the cell, mass transfer, thermodynamic and overpotential concepts needed before modeling a PEM electrolyzer in a process simulator.

Doğukan Ünal

IPEC Expert Opinion

Doğukan Ünal · Chemist, hydrogen technology expert ·

Understanding the losses inside the cell before dropping an electrolyser into a process simulator as a black box is the right order. According to the video description and chapter titles, the lesson moves through the cell model, mass transfer, thermodynamics and overpotentials. Cell voltage is the reversible voltage plus activation, ohmic and concentration losses. At 25 °C and 1 bar the reversible cell voltage for water splitting is about 1.23 V; the thermoneutral voltage is about 1.48 V. Simulation results should not be used as design data until model parameters are calibrated against a real polarisation curve. The content part of the description is short and relies mostly on section titles; the presenter is not named and the channel also points to paid courses.

— Doğukan Ünal

Do you have an electrolysis R&D project? Talk to an IPEC specialist about R&D collaboration.

Email: dunal(at)ipec.com.tr

Who is it for?

  • StudentCore concepts and a solid start
  • EngineerDesign, operation and system integration

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